@article{oai:shiga-med.repo.nii.ac.jp:00000511, author = {島脇, 孝典 and 青沼, 秀児 and 木村, 隆英 and 小松, 直樹}, journal = {滋賀医科大学基礎学研究}, month = {Mar}, note = {Departmental Bulletin Paper, Single-walled carbon nanotubes (SWCNTs) were attempted to be solubilized into organic solvent with the following monoporphyrins; 5,10,15,20-tetrakis(octadodecyloxyphenyl)-21H, 23H-porphyrin (TOPP-H2), 5,10,15,20-tetrahexylporphyrin (THP-H2), 5,15-bis(3,5-dioctyloxyphenyl)-2,8,12,18-tetradodecyl-3,7,13,17- tetramethylporphyrin (DPP-H2) and their Zn analogs. Only DPP-Zn solubilized a small amount of SWCNTs, though the rest of the porphyrins did not exhibit almost no solibilizing ability towards SWCNTs. The fact is in marked contrast to the large solubilizing ability of diporphyrins reported by us (N. Komatsu, et al., submitted for publication). The SWCNTs obtained through solubilization were found to be purified, but did not change in the diameter distribution and the ratio between metallic and semiconducting tubes. Although semiconducting SWCNTs were obtained separately through the solubilization with monoporphyrin analogous to TOPP-H2 (Y-P. Sun, et al, J. Am. Chem. Soc., 2004, 126, 1014), our attempt to trace the report merely provided almost no extraction of SWCNTs.}, pages = {45--52}, title = {モノポルフィリン化合物による単層カーボンナノチューブの可溶化}, volume = {13}, year = {2007} }